{"id":1740,"date":"2025-09-12T21:36:25","date_gmt":"2025-09-12T21:36:25","guid":{"rendered":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/outline_1\/"},"modified":"2025-09-12T21:49:09","modified_gmt":"2025-09-12T21:49:09","slug":"outline_1","status":"publish","type":"page","link":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/chem263\/outlines\/outline_1\/","title":{"rendered":"Lecture Outline 1"},"content":{"rendered":"<h1 align=\"left\">Chem 263 &#8211; Lecture Outline &amp; Assignment #1<\/h1>\n<p align=\"left\">\u00a0<\/p>\n<blockquote>\n<p><a href=\"#Readings\">Readings<\/a><br \/>\n  <a href=\"#Problems\">Problems<\/a><br \/>\n  <a href=\"#Outline\">Outline<\/a><br \/>\n  <a href=\"pdf\/C263_Out1_and_Assign1Sept16.pdf\" target=\"_blank\">Download pdf<\/a><\/p>\n<\/blockquote>\n<p align=\"left\">\u00a0<\/p>\n<h2><b><a name=\"Readings\" \/>Readings:<\/b><\/h2>\n<p \/>\n<p>TWG Solomons and CB Fryhle &#8220;Organic Chemistry&#8221; 11th Edition (2014):<\/p>\n<ul>\n<li>Functional Group List on page 76<\/li>\n<li>Periodic Table &#8211; Inside Front Cover (one page back from Inside Back Cover on earlier editions) <\/li>\n<li>Relative Strength of Acids and Bases on Inside Front Cover <\/li>\n<li>Chemical Shift Ranges in NMR \u2013 inside back cover facing page\u00a0 <\/li>\n<li>Chapter 9 &#8211; Nuclear Magnetic Resonance (NMR) Spectroscopy\n<ul>\n<li>  read all for overview<\/li>\n<li>study sections 9.1 to 9.12<\/li>\n<\/ul>\n<\/li>\n<li>Chapter 13 &#8211; Conjugated Unsaturated Systems<\/li>\n<\/ul>\n<p align=\"right\"><a href=\"#Top\"><img loading=\"lazy\" decoding=\"async\" src=\"..\/..\/images\/top_down.jpg\" alt=\"Top\" width=\"27\" height=\"16\" hspace=\"20\" border=\"0\" id=\"Top1\" \/><\/a>\n<\/p>\n<hr align=\"left\" width=\"100%\" \/>\n<p>\u00a0<\/p>\n<h2><b><a name=\"Problems\" id=\"Problems\" \/>Problems:<\/b><\/h2>\n<p> Do Not turn in, answers available in &#8220;Study Guide and Solutions Manual for Organic Chemistry&#8221; by Solomons and Fryhle.<\/p>\n<blockquote>\n<p><strong>Chapter 9:<br \/>\n    <\/strong>9.1 to 9.9 (both solved &amp; review problems); 9.16; 9.23; 9.24<\/p>\n<p><strong>Chapter 13:<br \/>\n    <\/strong>13.1 to 13.6 (both solved &amp; review problems); 13.20; 13.25; 13.35; 13.40; 13.45<\/p>\n<\/blockquote>\n<p align=\"right\"><a href=\"#Top\"><img loading=\"lazy\" decoding=\"async\" src=\"..\/..\/images\/top_down.jpg\" alt=\"Top\" width=\"27\" height=\"16\" hspace=\"20\" border=\"0\" id=\"Top2\" \/><\/a>\n<\/p>\n<hr align=\"left\" width=\"100%\" \/>\n<p>\u00a0<\/p>\n<h2><b><a name=\"Outline\" id=\"Outline\" \/><\/b><strong>Lecture Outline 1: Nuclear Magnetic Resonance (NMR) Spectroscopy, Conjugated Systems and Ultraviolet Spectroscopy<\/strong><\/h2>\n<p \/>\n<ol>\n<li><strong>Nuclear Magnetic Resonance (NMR) Spectroscopy\n<p>    <\/strong><\/p>\n<ol type=\"A\">\n<li>Electromagnetic Spectrum\n<\/li>\n<li>Principle of NMR and Instrumentation\n<\/li>\n<li>Proton Chemical Shift: Peak Position and Integration\n<ol>\n<li>Shielding and Deshielding of Hydrogens \u2013 Chemical Shifts<\/li>\n<li>Tetramethylsilane (TMS) standard<\/li>\n<li>Equivalent and Non-equivalent Hydrogens\n<\/li>\n<\/ol>\n<\/li>\n<li>Spin-Spin Splitting\n<\/li>\n<li>Basics of Carbon-13 NMR Spectroscopy\n<\/li>\n<li>Basics of 2D NMR Spectroscopy\n<p>\n        <\/li>\n<\/ol>\n<\/li>\n<li><strong>Conjugated Systems and Resonance<\/strong>\n<ol type=\"A\">\n<li>Nomenclature of Dienes and Allyl vs Vinyl\n<\/li>\n<li>Allyl Radical, Cation, and Anion &#8211; Stabilization\u00a0 and Resonance\n<\/li>\n<li>Addition Reactions of Dienes\n<\/li>\n<li>Allylic Radicals and Allylic Cations &#8211; Rubber and Polystyrene\n<\/li>\n<\/ol>\n<\/li>\n<li><strong>Energy Characteristics of Allylic Systems<\/strong>\n<ol type=\"A\">\n<li>Stability of Conjugated Dienes\n<ol>\n<li>Bond Lengths<\/li>\n<li>Conformation\n<\/li>\n<\/ol>\n<\/li>\n<li>Visible and Ultraviolet Spectroscopy\n<ol>\n<li>Measurement of spectra<\/li>\n<li>Absorption energies<\/li>\n<li>Biological significance\n<p>\n              <\/li>\n<\/ol>\n<\/li>\n<\/ol>\n<\/li>\n<li><strong>Electrocyclic Reactions of Alkene Systems\n<p>    <\/strong><\/p>\n<ol type=\"A\">\n<li>Diels-Alder and Retro Diels-Alder\n<ol>\n<li>General Form of reaction<\/li>\n<li>Stereochemistry<\/li>\n<\/ol>\n<\/li>\n<\/ol>\n<\/li>\n<\/ol>\n<p align=\"right\"><a href=\"#Top\"><img loading=\"lazy\" decoding=\"async\" src=\"..\/..\/images\/top_down.jpg\" alt=\"Top\" width=\"27\" height=\"16\" hspace=\"20\" border=\"0\" \/><\/a>\n<\/p>\n<hr align=\"left\" width=\"100%\" \/>\n<p>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chem 263 &#8211; Lecture Outline &amp; Assignment #1 \u00a0 Readings Problems Outline Download pdf \u00a0 Readings: TWG Solomons and CB Fryhle &#8220;Organic Chemistry&#8221; 11th Edition (2014): Functional Group List on page 76 Periodic Table &#8211; Inside Front Cover (one page back from Inside Back Cover on earlier editions) Relative Strength of Acids and Bases on <a href=\"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/chem263\/outlines\/outline_1\/\" class=\"more-link\">&#8230;<span class=\"screen-reader-text\">  Lecture Outline 1<\/span><\/a><\/p>\n","protected":false},"author":117,"featured_media":0,"parent":1199,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"templates\/chem263.php","meta":{"footnotes":""},"wf_page_folders":[7],"class_list":["post-1740","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/pages\/1740","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/users\/117"}],"replies":[{"embeddable":true,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/comments?post=1740"}],"version-history":[{"count":3,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/pages\/1740\/revisions"}],"predecessor-version":[{"id":1755,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/pages\/1740\/revisions\/1755"}],"up":[{"embeddable":true,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/pages\/1199"}],"wp:attachment":[{"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/media?parent=1740"}],"wp:term":[{"taxonomy":"wf_page_folders","embeddable":true,"href":"https:\/\/spaces.facsci.ualberta.ca\/vederaslab\/wp-json\/wp\/v2\/wf_page_folders?post=1740"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}